王辉       教授      博士生导师

▸办公室：花津校区绿帽奴 礼勤楼 516 室

▸实验室：花津校区绿帽奴 礼勤楼 509-510 室

▸Email:  [email protected]

教育背景

▸2007.09-2011.07      郑州大学              理学学士                  化学          （导师：崔秀灵教授）

▸2011.09-2014.07     郑州大学              理学硕士              有机化学      （导师：崔秀灵教授、吴养洁院士）

▸2014.10-2019.03     德国哥廷根大学   理学博士              有机化学      （导师：Prof. Dr. Lutz Ackermann）

工作经历

▸2019.04-2019.08        德国哥廷根大学       博士后      有机化学          （导师：Prof. Dr. Lutz Ackermann）

▸2019.09-2022.01      英国布里斯托大学    博士后      有机化学          （导师：Prof. Varinder Kumar Aggarwal）

▸2022.03-至今             绿帽奴             

主持项目和荣誉

▸德国DFG博士后研究项目 (442129649), 项目负责人 (), 2020.02-2022.01

▸绿帽奴 博士科研启动基金, 项目负责人, 2022.03-2025.02

▸国家自然科学基金青年科学基金项目 (22201010), 项目负责人, 2023.01-2025.12

▸安徽省高等学校科研计划优秀青年项目 (2022AH030024), 项目负责人, 2022.12-2025.11

▸安徽省海外引才计划青年项目 (2023)

▸安徽省自然科学基金优秀青年项目 (2308085Y09), 项目负责人，2023.09.01-2026.08.31

▸教育部第一批博士后海外引才专项, 项目负责人，2024.01.01-2026.12.31

▸人社部高层次留学人才回国资助, 项目负责人，2024.1.1-2026.12.31

研究领域

▸过渡金属催化合成方法学研究

▸可见光诱导的自由基反应研究

▸有机硼化合物的合成与转化研究

荣誉与获奖

▸德国博士毕业学位等级最高等 (Summa Cum Laude), 2019

▸河南省优秀硕士论文, 2014

学术成果

31) Y. Sun,^† L. Zhu,^† L. Zhang,* H. Wang,* Nickel-Catalysed Suzuki-Type Cross-Coupling of α-Iodosilanes with Arylboronic Acids: Direct and Efficient Access to Benzylic Silanes and gem-Silylboronate Esters, 17628. (^†Equal contribution)

30) L. Zhu, X. Zhang, H. Wang,* Nickel-Catalyzed C(sp³)–C(sp³) Coupling of Cyclopropanols via α-Bimetalloid Radicals: Access to γ-Carbonyl gem-Bis(boronates) and gem-Silylboronate Esters, . 

29) J. Wu,^† H. Wang,^† H. Fang, K. C. Wang, D. Ghosh, V. Fasano, A. Noble,* V. K. Aggarwal,* Persistent Boryl Radicals as Highly Reducing Photoredox Catalysts for Debrominative Borylations, . (^†Equal contribution)

28）Y. Sun, C. W. Zhu,* H. Wang,* Nickel-catalyzed C(sp²)−C(sp³) cross-coupling to access benzyl Bpins of arylboronic acids with α-halo boronic esters, .

27）L. Zhu, Y. Sun, H. Wang,* Ni-Catalyzed C(sp³)–C(sp³) Cross-Coupling to Access γ-Carbonyl Alkylboronates and Alkylsilicons Enabled by Cyclopropanol-Derived Homoenolates, .

26）X. Ling,^† Q. Zhao,^† X. Liu, Y. Wang, Y. Su, F. Yang, Z. Zhang,* H. Wang,* Y. Shang,* L. Fu,* Deoxygenative Cyclopropanation of Aldehydes with Acyl-Stabilized Sulfur Ylides, . (^†Equal contribution)

25) H. Sun, S. Chen,* H. Wang,* Metal- and Base-free Selective Amidations of Organoboronic Acids with Dioxazolones and Isocyanates, .

24) Y. Sun,^† Y. Wang,^† L. Zhang,* R. Zhong,* H. Wang,* Synthesis of Bridged and Fused Tetracycles via Rhodium-Catalyzed C−H Allylation/Cycloaddition of Azomethine Imines with MBH Adducts and Allyl acetates, . (^†Equal contribution)

23) S. Zeng,^†Y. Zeng,^† H. Wang,* P. Sun,* Z. Ruan,* Regio- and Stereoselective Synthesis of 3-Selenylazaflavanones and 3-Selenylflavanones via Electrochemically Facilitated Selenylation Cascade. . (^†Equal contribution)

22) H. Balati, J. Zhu, W. Xu, H. Wang,* X. Hu,* Z. Ruan,* Solvent-Regulated Electrochemical Selenylation and Deuteration of Alkynyl Aryl Ketones: Chemoselective Synthesis of 3-Selenylated Chromones and Deutero-Selenylated Chalcones. .

21) H. Wang,^† W. Han,^† A. Noble, V. K. Aggarwal,^* Dual Nickel/Photoredox-Catalyzed Site-selective Cross-Coupling of 1,2-Bis-Boronic Esters Enabled by 1,2-Boron Shifts. . (^†Equal contribution)

20) H. Wang, J. Wu, A. Noble, V. K. Aggarwal,* Selective Coupling of 1,2-Bis-Boronic Esters at the more Substituted Site through Visible-Light Activation of Electron Donor-Acceptor Complexes. .

19)  H. Wang,^† C. Jing,^† A. Noble, V. K. Aggarwal,* Stereospecific 1,2‐Migrations of Boronate Complexes Induced by Electrophiles. . (^†Equal contribution)

18) H. Wang,^† N. Kaplaneris,^† L. Ackermann, Allenes in Manganese(I)-Catalyzed C–C Activation and A Strategy for Cascade Ring-Expansion. . (^†Equal contribution)

17) H. Wang,^† I. Choi,^† T. Rogge, N. Kaplaneris, L. Ackermann,* Versatile and Robust C–C Activation by Chelation-Assisted Manganese-Catalysis. . (^†Equal contribution)

16) H. Wang,^† F. Pesciaioli,^† J. C. A. Oliveira, S. Warratz, L. Ackermann,* Synergistic Manganese(I) C−H Activation Catalysis in Continuous Flow: Chemoselective Hydroarylation. . (^†Equal contribution)

15) H. Wang,^† M. M. Lorion,^† L. Ackermann,* Air-Stable Manganese(I)-Catalyzed C–H Activation for Decarboxylative C–H/C–O Cleavages in H₂O. . (^†Equal contribution)

14) H. Wang,^† M. M. Lorion,^† L. Ackermann,* Overcoming the Limitations of C−H Activation with Strongly Coordinating N-Heterocycles by Cobalt Catalysis. A. (Highlight by Synfacts 2016, 12, 1126) (^†Equal contribution)

13) H. Wang, M. M. Lorion, L. Ackermann,* Domino C–H/N–H Allylations of Imidates by Cobalt Catalysis. .

12) H. Wang, M. Moselage, M. J. González, L. Ackermann,* Selective Synthesis of Indoles by Cobalt(III)-Catalyzed C−H/N−O Functionalization with Nitrones. .

11) H. Wang, J. Koeller, W. Liu, L. Ackermann,* Cobalt(III)-Catalyzed C–H/N–O Functionalizations: Isohypsic Access to Isoquinolines. .

10) H. Wang, X. Cui,* Y. Pei, Q. Zhang, J. Bai, D. Wei, Y. Wu,* Direct Regioselective Phosphonation of Heteroaryl N-oxides with H-phosphonates under Metal and External Oxidant Free Conditions. .

9) H. Wang, Y. Pei, J. Bai, J. Zhang, Y. Wu,* X. Cui,* Dimerization of Heteroaromatic N-oxides Under Metal-Free Conditions. .

8) A. Çapcı, M. M. Lorion, H. Wang, N. Simon, M. Leidenberger, M. C. Borges Silva, D. R. M. Moreira, Z. Yongping, M. Yuqing, C. J. Yun, Y. M. Lee, O. Friedrich, B. Kappes, J. Wang, L. Ackermann,* S. B. Tsogoeva,* Artemisinin‐(Iso)Quinoline Hybrids by C‐H Activation and Click Chemistry: Combating Multidrug‐Resistant Malaria. .

7) N. Kaplaneris, T. Rogge, R. Yin, H. Wang, G. Sirvinskaite, L. Ackermann,* Late-Stage Diversification by Manganese-Catalyzed C–H Activation: Access to Acyclic, Hybrid and Stapled Peptides. .

6) S. R. Yetra, Z. Shen, H. Wang, L. Ackermann,* Thiocarbonyl-Enabled Ferrocene C–H Nitrogenation by Cobalt(III) Catalysis: Thermal and Mechanochemical. .

5) R. Mei, H. Wang, S. Warratz, S. A. Macgregor, L. Ackermann,* Cobalt-Catalyzed Oxidase C–H/N–H Alkyne Annulation: Mechanistic Insights and Access to anti-Cancer Agents. .

4) Q. Zhang, X. Cui,* L. Zhang, S. Luo,* H. Wang, Y. Wu,* Redox Tuning of a Direct Asymmetric Aldol Reaction, .

3) Q. Zhang, D. Wei, X. Cui,* D. Zhang, H. Wang, Y. Wu,* Direct Diphosphonylation of Quinolines with H-phosphonates under Metal-Free Conditions, .

2) J. Bai, X. Cui,* H. Wang, Y. Wu,* Copper-Catalyzed Reductive Coupling of Aryl Sulfonyl Chlorides with H-phosphonates Leading to S-aryl Phosphorothioates, .

1) H. Zhang, X. Cui,* X. Yao, H. Wang, J. Zhang, Y. Wu*, Directly Fused Highly Substituted Naphthalenes via Pd-Catalyzed Dehydrogenative Annulation of N,N-Dimethylaminomethyl Ferrocene Using a Redox Process with a Substrate. .